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Material Investigation

Sheets
Plates / Billets / Rods

 

Sheets:

AMTS monitors and spots all suppliers of industrial magnesium sheets, which are rather scarce.
We also have in stock significant amount of sheets in different thicknesses (see wrought alloys properties).

Before we start using new alloys or new source for a process we examine thoroughly the sheet properties, such as:
σy/UTS ratio, homogenous elongation, anisotropy values, strain herdening exponent, strain rate sensitivity and multi-directional behavior test - analysis
of forming limit diagram, cup test and superplastic behavior.

Due to the Hexagonal Close-Packed (HCP) structure of the magnesium crystal, it has very poor plasticity at room temperature but quite good formability
at teperature range of 200°C to 350°C. The thermal dislocations system activates when temperature reaches 220°C.
We also investigate the superplastic formability of magnesium sheets while the main topics are the effects of microstructure (particularly grain size).

Alloys: Suitable alloys for drawing of magnesium sheets, which presently appear in the literature, are:
AZ31B-O, AZ61A, HK31A-O, HM21A-T8, ZA10-O (definitions according to ASTM B 275).

Typical values:

Yet, there are no formal values of anisotrpy coefficient (r) and strain herdening coefficient (n) for magnesium alloys. Those are super-relevant parameters for deep drawing and stretch forming processes.
Vertical anisotropy [r=j/j (thickness/width)] is measured in simple tensile tests by finding the logarithmic strain in each direction.
Average anisotropy of r > 1 is a key factor as long as causing good material flow out of the sheet plane and provides relatively small thickness reduction.
Strain hardening exponent (n) equals to the material flow curve gradient in a logarithmic presentation. This exponent measures the strength increase.
High n coefficient reduces the local strain concentration in case of tensile stresses and therefore leads to high elongation and maximum formability in stretch forming process.
It is advisable to mention that test direction (rolling or other directions) affects anisotropy results. On the other hand directionality has less effect on strain hardening coefficient (n).

Forming limit diagram analysis:

 This examination process is done by specimen test of typical sheets from different alloys.
The examination goal is to create a failure limit curve of the bi-directional plane strains.

 Major deformation in deep drawing process occurs by plain stress. The strain percentage is limited as dependency in the activated stress along each axis as well as the anisotrpy coefficient (which very much depends on sheet rolling procedure).

dd investigation.jpg
FLD 1.JPG FLD 2.JPG

Cup test:

The goal in cup testing is to examine the feedstock behavior in a lab-scale deep drawing process for given criterions, such as blankholder pressure, deformation rate, temperature and lubrication.
The typical criterion for evaluating suitabilness of magnesium sheet to a deep drawing process is the drawing ratio (D/d) in a pre-failure state. Additionally, cup test can give idea about plane anisotropy (rolling direction - transverse direction plane) of the sheet.
On the other hand, during the recent development processes at AMTS, we use cup test results to fit new lubricants.

cup.JPG
cups.JPG cupisotropy.JPG
force-punchstroke.jpg cupcut28.jpg


Superplasic behavior:

Superplasticity is the ability of some materials to develop very large tensile elongations (up to hundreds and thousands percents) without necking. There are several requirements for a material to be able to exhibit superplasticity:

  • Fine and equiaxed microstructure (grain size generally < 10 µm)
  • Grains stable under high temperature: Temperature higher than 0.4 Tm (absolute melting point)
  • Strain rate sensitivity exponent) M)

Scientific studies show that the deformation rate depends strongly on the grain size of the magnesium alloy. The resulting observation is that the smaller the grains size the higher the deformation rate of the SPF. Such refining of grain size could be achieved by pre-treatment either by plastic deformation of the feedstock, additives intended to refine grains (e.g. Zr) and proper heat treatment. For illustration: it was observed that ZK60 could be brought to an elongation of 1330% when it had grain size of 3.7µm (see the figure on the right).

elongation.jpg

When we examine the suitability of magnesium sheet to SPF process we run several procedures:

  • We test tensile samples in a certain temperature range and in different strain rates.
  • We examine microstructure to identify pre-process grain size.
  • We run small scale multi-directional stretching process.

So far we examined in AMTS the following alloys: AZ31B, ZK10, MA20.

Superplastic behavior of the sheets was evaluated in the temperature range 573-693°K and compared to that of the initial materials having relatively coarse grains. Existing deformation mechanism maps for FCC and BCC metals were reviewed and found to be deficient in predicting the deformation behavior of magnesium alloys with HCP crystal structure.

Using the experimental data for a number of magnesium alloys, which are associated with various deformation mechanisms competing at elevated temperatures, deformation mechanism maps for magnesium alloys were constructed. Excellent prediction capability of the maps was verified at temperatures of 573–673°K.

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Plates / Billets / Rods:

AMTS monitors and spots all sources of industrial magnesium rolled plates and extrusions, which are rather scarce.
We also hold in a quite big stock, rolled plates and extruded bars in different sizes.

Properties and material behavior:
For optimal forging, the control of feedstock parameters beyond alloy composition should be the key. Principle of these is the control of microstructure properties such as grain size and the distribution of second phase particles. Within an alloy type such as AZ80 or ZK60, wide vvariation of these aspects can be achieved, resulting in wide variation in the suitability for Forging.

For cost effective forging there is a choice of DC cast billet or pre-worked bar or plate.
This choice also greatly influences forgability. Techniques that will be used to evaluate the structure and its relationship with forgeability will include mechanical behavior, structural analysis and measurement of texture and the use of EM techniques such as EBSD mapping.
As new alloys or magnesium matrix, currently being developed, become available, these techniques will also be applied to optimize these alloys for forging.
 
New Magnesium base material Applications:
AMTS research center, the Metal Institute and the Material Engineering Faculty of the TECHNION (project leaders), together with the extrusion company ALUBIN LTD, have established several of novel magnesium base processes which soon will provide a state of the art pre-forge feedstock with the following proerties:
  • Very high strength magnesium base billets out of combination of TECHNION patented alloying and rapid solidification process.
congested billet.jpg
  • Magnesium billets with High deformation ratio at relatively low temperatures: by modification of conventional alloys (such as ZK60) into thixotrophic structure.
ZK60 microstructure.jpg
  • Under research: for high temperatures (up to 150°C) applications by MMC.

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